One-Step Formation of Morphologically Controlled Nanoparticles with Projection Coronas
Identifieur interne : 001802 ( Main/Exploration ); précédent : 001801; suivant : 001803One-Step Formation of Morphologically Controlled Nanoparticles with Projection Coronas
Auteurs : Tatsuo Kaneko [Japon] ; Kazuhiro Hamada [Japon] ; Ming Qing Chen [Japon] ; Mitsuru Akashi [Japon]Source :
- Macromolecules [ 0024-9297 ] ; 2003.
Abstract
Nanoparticles with projection coronas were prepared by the one-step dispersion terpolymerization of styrene, acrylonitrile, and poly(ethylene glycol) monomethacrylate in ethanol−water solution, and their morphologies were controlled. When the mole composition of acrylonitrile to the total monomers CAN was 0.49−0.66, electron microscopy showed that the nanoparticles were spherical and had a number of projections on the surface. A CAN of more than 0.66 yielded no nanospheres, and a CAN smaller than 0.49 yielded projection-free nanospheres. The morphology of the nanospheres could be controlled by changing the reaction conditions, and some conditions yielded a regular arrangement of uniform projections on the surface similar to that seen in some coronaviruses. X-ray and spectroscopic studies suggested that the projections might be formed as a result of the nonequilibrated swelling of acrylonitrile and poly(ethylene glycol) domains on the surface.
Url:
DOI: 10.1021/ma035276g
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000524
- to stream Istex, to step Curation: 000491
- to stream Istex, to step Checkpoint: 000270
- to stream Main, to step Merge: 001813
- to stream Main, to step Curation: 001802
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>One-Step Formation of Morphologically Controlled Nanoparticles with Projection Coronas</title><author><name sortKey="Kaneko, Tatsuo" sort="Kaneko, Tatsuo" uniqKey="Kaneko T" first="Tatsuo" last="Kaneko">Tatsuo Kaneko</name></author><author><name sortKey="Hamada, Kazuhiro" sort="Hamada, Kazuhiro" uniqKey="Hamada K" first="Kazuhiro" last="Hamada">Kazuhiro Hamada</name></author><author><name sortKey="Chen, Ming Qing" sort="Chen, Ming Qing" uniqKey="Chen M" first="Ming Qing" last="Chen">Ming Qing Chen</name></author><author><name sortKey="Akashi, Mitsuru" sort="Akashi, Mitsuru" uniqKey="Akashi M" first="Mitsuru" last="Akashi">Mitsuru Akashi</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:C26B896B26BA366DA46A40CF802D1C15D05110BD</idno><date when="2004" year="2004">2004</date><idno type="doi">10.1021/ma035276g</idno><idno type="url">https://api.istex.fr/ark:/67375/TPS-XFQXHX91-M/fulltext.pdf</idno><idno type="wicri:Area/Istex/Corpus">000524</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000524</idno><idno type="wicri:Area/Istex/Curation">000491</idno><idno type="wicri:Area/Istex/Checkpoint">000270</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000270</idno><idno type="wicri:doubleKey">0024-9297:2004:Kaneko T:one:step:formation</idno><idno type="wicri:Area/Main/Merge">001813</idno><idno type="wicri:Area/Main/Curation">001802</idno><idno type="wicri:Area/Main/Exploration">001802</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">One-Step Formation of Morphologically Controlled Nanoparticles with
Projection Coronas</title><author><name sortKey="Kaneko, Tatsuo" sort="Kaneko, Tatsuo" uniqKey="Kaneko T" first="Tatsuo" last="Kaneko">Tatsuo Kaneko</name><affiliation wicri:level="1"><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Nanostructured and Advanced Materials, Graduate School of Science and Engineering,Kagoshima University, 1-21-40, Korimoto, Kagoshima 890-0065, Japan; School of Chemical andMaterial Engineering, Southern Yangtze University, Wuxi 214036, P. R. China; and Department ofMolecular Chemistry, Graduate School of Engineering, Osaka University,2-1, Yamada-oka, Suita 565-0871, Japan and CREST, JST, 4-1-8, Hommachi,Kawaguchi, 332-0012</wicri:regionArea><wicri:noRegion>332-0012</wicri:noRegion></affiliation><affiliation></affiliation></author><author><name sortKey="Hamada, Kazuhiro" sort="Hamada, Kazuhiro" uniqKey="Hamada K" first="Kazuhiro" last="Hamada">Kazuhiro Hamada</name><affiliation wicri:level="1"><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Nanostructured and Advanced Materials, Graduate School of Science and Engineering,Kagoshima University, 1-21-40, Korimoto, Kagoshima 890-0065, Japan; School of Chemical andMaterial Engineering, Southern Yangtze University, Wuxi 214036, P. R. China; and Department ofMolecular Chemistry, Graduate School of Engineering, Osaka University,2-1, Yamada-oka, Suita 565-0871, Japan and CREST, JST, 4-1-8, Hommachi,Kawaguchi, 332-0012</wicri:regionArea><wicri:noRegion>332-0012</wicri:noRegion></affiliation><affiliation></affiliation></author><author><name sortKey="Chen, Ming Qing" sort="Chen, Ming Qing" uniqKey="Chen M" first="Ming Qing" last="Chen">Ming Qing Chen</name><affiliation wicri:level="1"><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Nanostructured and Advanced Materials, Graduate School of Science and Engineering,Kagoshima University, 1-21-40, Korimoto, Kagoshima 890-0065, Japan; School of Chemical andMaterial Engineering, Southern Yangtze University, Wuxi 214036, P. R. China; and Department ofMolecular Chemistry, Graduate School of Engineering, Osaka University,2-1, Yamada-oka, Suita 565-0871, Japan and CREST, JST, 4-1-8, Hommachi,Kawaguchi, 332-0012</wicri:regionArea><wicri:noRegion>332-0012</wicri:noRegion></affiliation><affiliation></affiliation></author><author><name sortKey="Akashi, Mitsuru" sort="Akashi, Mitsuru" uniqKey="Akashi M" first="Mitsuru" last="Akashi">Mitsuru Akashi</name><affiliation wicri:level="1"><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Nanostructured and Advanced Materials, Graduate School of Science and Engineering,Kagoshima University, 1-21-40, Korimoto, Kagoshima 890-0065, Japan; School of Chemical andMaterial Engineering, Southern Yangtze University, Wuxi 214036, P. R. China; and Department ofMolecular Chemistry, Graduate School of Engineering, Osaka University,2-1, Yamada-oka, Suita 565-0871, Japan and CREST, JST, 4-1-8, Hommachi,Kawaguchi, 332-0012</wicri:regionArea><wicri:noRegion>332-0012</wicri:noRegion></affiliation><affiliation></affiliation><affiliation></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Japon</country></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Macromolecules</title><title level="j" type="abbrev">Macromolecules</title><idno type="ISSN">0024-9297</idno><idno type="eISSN">1520-5835</idno><imprint><publisher>American Chemical Society</publisher><date type="e-published" when="2003-12-23">2003</date><date when="2004-01-27">2004</date><biblScope unit="vol">37</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="501">501</biblScope><biblScope unit="page" to="506">506</biblScope></imprint><idno type="ISSN">0024-9297</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0024-9297</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract">Nanoparticles with projection coronas were prepared by the one-step dispersion terpolymerization of styrene, acrylonitrile, and poly(ethylene glycol) monomethacrylate in ethanol−water solution, and their morphologies were controlled. When the mole composition of acrylonitrile to the total monomers CAN was 0.49−0.66, electron microscopy showed that the nanoparticles were spherical and had a number of projections on the surface. A CAN of more than 0.66 yielded no nanospheres, and a CAN smaller than 0.49 yielded projection-free nanospheres. The morphology of the nanospheres could be controlled by changing the reaction conditions, and some conditions yielded a regular arrangement of uniform projections on the surface similar to that seen in some coronaviruses. X-ray and spectroscopic studies suggested that the projections might be formed as a result of the nonequilibrated swelling of acrylonitrile and poly(ethylene glycol) domains on the surface.</div></front></TEI><affiliations><list><country><li>Japon</li></country></list><tree><country name="Japon"><noRegion><name sortKey="Kaneko, Tatsuo" sort="Kaneko, Tatsuo" uniqKey="Kaneko T" first="Tatsuo" last="Kaneko">Tatsuo Kaneko</name></noRegion><name sortKey="Akashi, Mitsuru" sort="Akashi, Mitsuru" uniqKey="Akashi M" first="Mitsuru" last="Akashi">Mitsuru Akashi</name><name sortKey="Akashi, Mitsuru" sort="Akashi, Mitsuru" uniqKey="Akashi M" first="Mitsuru" last="Akashi">Mitsuru Akashi</name><name sortKey="Chen, Ming Qing" sort="Chen, Ming Qing" uniqKey="Chen M" first="Ming Qing" last="Chen">Ming Qing Chen</name><name sortKey="Hamada, Kazuhiro" sort="Hamada, Kazuhiro" uniqKey="Hamada K" first="Kazuhiro" last="Hamada">Kazuhiro Hamada</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Sante/explor/CovidV2/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001802 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001802 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Sante
|area= CovidV2
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:C26B896B26BA366DA46A40CF802D1C15D05110BD
|texte= One-Step Formation of Morphologically Controlled Nanoparticles with Projection Coronas
}}
| This area was generated with Dilib version V0.6.33. |  |